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Accurate measurement of neptunium ionization potential using new laser technology

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2024-05-11 16:42:14
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Neptunium is the main radioactive component of nuclear waste, with a complex atomic structure that can be explored through mass spectrometry. This analysis is crucial for understanding its inherent characteristics and determining the isotopic composition of neptunium waste. Magdalena Kaja and her team from Johannes Gutenberg University in Mainz, Germany have developed a novel laser spectroscopy technique that can more accurately measure the ionization potential of neptunium compared to previous methods.

Neptunium is an actinide metal in the periodic table adjacent to uranium, with an atomic number of 93. The inspiration for its name comes from Neptune, located outside of Uranus in the solar system, which is a recognition of its position. Among the 25 known isotopes, most have extremely short lifetimes. However, the most stable isotope, neptunium 237 (237 Np), has a half-life of over 2 million years, making it a particularly dangerous nuclear pollutant.

The neptunium isotope samples available for this type of analysis are very small: they typically only contain a few atoms of the isotope.


Magdalena Kaja and her colleagues utilized a cutting-edge device that includes solid-state titanium: sapphire laser systems, enhanced laser ion sources, and high transmittance mass separators. This advanced equipment has played an important role in their research on neptunium.

The research team used this technique to measure the first ionization energy of neptunium, which is the energy required to remove the first electron from the outermost electron shell to form a positive ion. They accurately determined the value to be 6.265608 (19) eV. This measurement is not only consistent with the values previously reported in scientific literature, but also achieves an accuracy level more than ten times higher than any previous measurement.

This method can also be applied to the analysis and detection of trace amounts of neptunium in radioactive waste.

Source: Laser Net

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