chanelink logo
CHANELINK
Italiano

Progress has been made in the corrosion mechanism of alkali aluminum phosphate glass at Shanghai Optics and Machinery Institute

370
2024-07-10 14:33:18
Vedi traduzione

Recently, the Advanced Laser and Optoelectronic Functional Materials Department of the Shanghai Institute of Optics and Precision Mechanics, Chinese Academy of Sciences, has made new progress in the corrosion mechanism of alkali aluminophosphate glass. The research findings were published in The Journal of Physical Chemistry C under the title "Formation Mechanism of Crystal Phase during Corrosion of Aluminum Phosphate Glasses".

Alkaline aluminum phosphate glass has important applications in the solidification of nuclear waste glass and other fields. Among them, chemical stability is crucial for its application. To gain a deeper understanding of the chemical stability of glass, it is necessary to understand its chemical corrosion mechanism. The study of glass corrosion mechanisms has a long history, but there are still many controversies. Previous research has mainly focused on borosilicate glass, while there has been less research on the corrosion mechanism of phosphate glass.

In this study, researchers conducted atomic scale analysis of the structure of alkali aluminum phosphate glass before and after corrosion using various advanced nuclear magnetic resonance techniques, and found that there were two different dissolution modes of the Q1 and Q0 groups in the glass in aqueous solution. This confirms that the crystal layer on the surface of phosphate glass originates from the dissolution of glass components and subsequent deposition on the glass surface. Revealed the dissolution mechanism of alkaline aluminum phosphate glass in aqueous solution and the formation mechanism of surface crystal layer. The research results deepen our understanding of the chemical stability mechanism of alkaline aluminum phosphate glass.

(a) The two dissolution modes of glass. (b) 27Al {27Al} 2D WURST 2Q-1Q spectrum of corroded glass

Source: Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences

Raccomandazioni correlate

  • Lockheed Martin announces expansion of 16000 square feet 3D printing center

    Recently, US military industry giant Lockheed Martin announced that it will significantly increase its additive manufacturing capabilities and expand its factory in Texas. The expansion project includes approximately 16000 square feet of dedicated space for 3D printing technology, and the addition of some of the largest large format multi laser printers in the space (it is worth noting that Lockhe...

    2024-12-02
    Vedi traduzione

  • Aerotech announces new control features for laser scanning heads

    Aerotech has upgraded the performance of AGV laser scanning heads through powerful controller functions to enhance scanner control (ESC). The new ESC function of the Automation 1-GL4 2-axis laser scanning head driver is a completely passive control loop enhancement function that ensures higher accuracy in the most dynamic motion.With the increasing demand for higher output laser technology in vari...

    2024-06-04
    Vedi traduzione

  • Researchers at the Technion-Israel Institute of Technology have developed coherently controlled spin optical lasers based on single atomic layers

    Researchers at the Technion-Israel Institute of Technology have developed a coherently controlled spin optical laser based on a single atomic layer.This discovery was made possible by coherent spin-dependent interactions between a single atomic layer and a laterally constrained photonic spin lattice, which supports a high-Q spin valley through Rashaba-type spin splitting of photons of bound states...

    2023-09-12
    Vedi traduzione

  • Thorlabs announces acquisition of Praevium Research

    On January 13, 2025, Thorlabs announced the acquisition of long-term partner Praevium Research, a developer of high-speed tunable VCSEL. In the future, Praevium will continue to operate as a department of Thorlabs under the name Praevium Research at its existing locations in California, while retaining its current leadership.It is understood that Christopher Burgner will serve as the general man...

    01-16
    Vedi traduzione

  • Shanghai Optics and Machinery Institute has made progress in the research of new terahertz sources based on Yb lasers

    Recently, the State Key Laboratory of Intense Field Laser Physics of the Chinese Academy of Sciences Shanghai Institute of Optics and Fine Mechanics has made new progress in generating intense field terahertz waves based on Yb laser pumped organic crystals. The relevant research results were published in Applied Physics Letters under the title "Efficient strong field THz generation from DSTMS crys...

    2024-04-09
    Vedi traduzione